MINERALS INDEX

Actinolite

Albite

Allactite

Allanite

Amphibole Group

Andradite

Anglesite

Anhydrite

Anorthite

Apatite

ApatiteGroup

Apophyllite

Aragonite

Arsenates

Arsenides

Arseniosiderite

Arsenopyrite

Aurichalcite

Axinite

Azurite

Barite

Barylite

Barysilite

Bementite

Biotite

Borates

Bornite

Boroarsenates

Bustamite

Cahnite

Calamine

Calcite

Calcium larsenite

Carbonates

Celestite

Cerusite

Chalcocite

Chalcophanite

Chalcopyrite

Chloanthite

Chlorite

Chlorophoenicite

Chondrodite

Chysolite Group

Clinohedrite

Copper

Corundum

Corundum Group

Crocidolite

Cummingtonite

Cuprite

Cuspidine

Cyprine

Datolite

Desaulesite

Descloizite

Diopside

Dolomite

Edenite

Epidote

EpidoteGroup

FeldsparGroup

Ferroaxinite

Ferroschallerite

Fluoborite

Fluorite

Franklinite

Friedelite

Friedelite Group

Gageite

Gahnite

Galena

Ganophyllite

Garnet

Glaucochroite

Goethite

Graphite

Greenockite

Gypsum

Halloysite

Haloids

Hancockite

Hardystonite

Hastingsite

Hedyphane

Hematite

Hetaerolite

Heulandite

Hodgkinsonite

Holdenite

Humite Group

Hyalophane

Hydrohetaerolite

Hydrozincite

Ilmenite

Jeffersonite

Kentrolite

Larsenite

Lead

Leucaugite

Leucophoenicite

Limonite

Lollingite

Loseyite

Magnesium- chlorophoenicite

Magnetite

Malachite

Manganbrucite

Manganite

Manganosite

Marcasite

Margarosanite

Mcgovernite

Mica Group

Microcline

Millerite

Molybdenite

Mooreite

Muscovite

Nasonite

Native Elements

Neotocite

Niccolite

Norbergite

Oxides

Pargasite

Pectolite

Phlogopite

Phosphates, Arsenates and Vanadates

Prehnite

Psilomelane

Pyrite

Pyrochroite

Pyroxene Group

Pyrrhotite

Quartz

Rhodochrosite

Rhodonite

Roeblingite

Roepperite

Rutile

Scapolite

Schallerite

Schefferite

Serpentine

Serpentine Group

Siderite

Silicates

Silver

Smithsonite

Sphalerite

Spinel

Spinel Group

Stilbite

Sulphates

Sulphides and Arsenides

Sussexite

Svabite

Talc

Tennantite

Tephroite

Thomsonite

Thorite

Titanite

Tourmaline

Tremolite and Actinolite

Unconfirmed Species

Vanadates

Vesuvianite

Willemite

Xonotlite

Zeolites

Zinc schefferite

Zincite

Zircon

Zoisite

 

Larsenite

PbZnSiO4
Orthorhombic

Crystallographic elements
Computation based on the measurement of 40 faces, distributed among 5 forms, gives the result a : b : c = 0.4339 : 1 : 0.5324; po = 1.2268, qo = 0.5324.

Forms
a(190), b(010), m(110), n(210), s(120), y(150), d(101), w(012), e(111), q(122), t(132), A(142), l(131), C(252), and B(9.8.18).

Combinations on crystals of larsenite
  Forms Illustrations
1 b, a, m, s, A, B Figure 112
2 b, m, s, w, A, C, B Figure 113
3 b, m, s, y, q, t, A Figure 114
4 b, s, A Figure 115
5 a, n, m, s, w, e, A, B  
6 b, m, s, w, e, A, C, B  
7 n, m, s, t, A, l  
8 b, m, d, e, A, B  

Habit
The crystals of larsenite are slender needles 10 to 20 times as long as they are thick, forming an interlacing network in vein cavities. Many of them reach from wall to wall and show no terminations, but a few stand with one end free and can be detached for measurement. Rarely the mineral has the form of thin lustrous plates.

The prism zone is generally rounded by striation, only one measured crystal showing a pronounced flattening parallel to the brachypinacoid. The prism s(120), to which the cleavage is parallel, was seen on all the crystals and gives good reflections, whereas in m(110), n(210), and y(150) are only narrow linear faces.

The termination is generally dominated by the pyramid A(142), whose faces are excellent and give consistent readings.

Figure 112 shows the prevailing habit; in figure 113 the brachydome is added; figure 114 shows it habit seen on but one crystal; and the platy habit is illustrated in figure 115.

Figure 112
Prismatic crystal of larsenite showing the usual termination, with the forms b(010), m(110), s(120), A(142), and B(9.8.18). Franklin.
fig112.gif (4891 bytes)
fig113.gif (4925 bytes) Figure 113
Plan of a prismatic crystal of larsenite showing the forms of figure 112 and also w(012). Franklin.
Figure 114
Plan of a prismatic crystal of larsenite showing the forms m(110), s(120), q(122), t(132), and A(142). Franklin.
fig114.gif (4630 bytes)
fig115.gif (2532 bytes) Figure 115
Plan of a crystal of larsenite of tabular habit, showing the forms b(010), s(120), and A(142). Franklin.

Forms not shown in the figures are subordinate and are generally seen only as linear faces. The needles are very slender, so that the terminal faces on all crystals are exceedingly minute. Because of the high luster of the mineral, however, they give good measurements despite their small size.

Composition
The following analysis shows the composition of larsenite:

Analysis of larsenite
 

1

2

SiO2

16.87

16.47

PbO

56.66

61.21

ZnO

22.74

22.32

FeO

0.10

 
MnO

0.14

 
CaO

2.42

 
MgO

0.20

 
H2O

0.76

 
 

99.89

100.00

1. Larsenite, containing 9.26 percent of clinohedrite. L. H. Bauer (256), analyst.
2. Composition computed from formula adopted.

 

The material analyzed was known to contain clinohedrite, and the lime and water found were regarded as due to that mineral. After deducting 9.26 percent of clinohedrite, the remainder gave a ratio fairly close to that required by the formula PbZnSiO4, which is therefore adopted as the formula of larsenite.

Occurrence
Larsenite was first found in 1928 and, with the closely related calcium larsenite, was described in papers by Palache, Bauer, and Berman (256, 259). The first specimens were found on the picking table at Franklin, and the mineral was afterward located in the mine at the north end, 20 feet above the 400-foot level in top slice 1080. Part of the specimens are in veins cutting ore, and part have replaced rather coarse, massive willemite-franklinite ore. The veins are sharply bounded against the granular ore and differ in their contents from place to place.

The earliest mineral to form was a massive pink garnet, identical in appearance and refractive index (1.885) with garnet from another specimen, shown by partial analysis to be andradite. Upon this is a coating of hodgkinsonite of the same pink color as the massive garnet. Most surfaces of the open veins show rather indistinct crystals, with rounded faces, of pale-pink to almost colorless hodgkinsonite. In several specimens devoid of lead silicates the only minerals later than hodgkinsonite are calcite in slender needles or clear prismatic crystals, botryoidal coatings of smithsonite, granular orange-colored zincite, and a last coating of snow-white needles of willemite forming delicate rosettes. In other parts of the open veins hodgkinsonite was followed by an abundant layer of crystalline clinohedrite with which the slender needles and plates of larsenite are contemporaneous. A few spots of dull white massive roeblingite covering clinohedrite crystals, were found in one of the specimens. Larsenite is far less abundant than calcium larsenite, and in most specimens the two are not associated, but in two places crystals of larsenite were found in cavities with calcium larsenite. Furthermore, larsenite is found only in the vein material and not in the replaced ore.

It is worthy of note, in view of the discovery of these lead silicates, that in two analyses of glaucochroite (see page 79) some lead is reported, indicating the possible presence of the larsenite molecule.

 


 
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