MINERALS INDEX
Gageite |
| 4(Mn,Mg,Zn)(OH)2.6(Mn,Mg,Zn)2SiO4.3H2O |
| Orthorhombic |
Character
Gageite forms minute colorless or pink needles or laths with a high vitreous
luster, grouped radially, in bundles, or matted together. It appears to be
orthorhombic and is optically negative; 2V moderate; r < v (extreme)
Z parallel to the fibers. Lying on the chief crystal face, which is
probably the unit prism, the laths show the emergence of X on the edge
of the field; a
= 1.723, b = 1.734,
g = 1.736, all
±0.003 (Larsen). The specific gravity is 3.584.
Composition
Gageite is a hydrous silicate of manganese, zinc, and magnesium. The molecular
ratio of RO : SiO2 : H2O is 16 : 6 : 7, from which is
derived the formula given above. The mineral was believed by Phillips (196)
to be chemically akin to leucophoenicite.
|
1 |
2 |
3 |
||
| SiO2 |
24.71 |
23.58 |
0.392 | = 6 x 0.065 |
| MnO |
50.19 |
53.74 |
0.758* | |
| MgO |
11.91 |
9.95 |
0.247* | 1.053 = 16 x 0.066 |
| ZnO |
8.86 |
3.96 |
0.049* | |
| FeO |
0.03 |
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| Al2O3 |
0.15 |
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| H2O |
4.43a |
8.24 |
0.457 | = 7 x 0.065 |
|
100.00 |
99.65 |
|||
| [* figures reflected in the value 1.053 shown.] |
| a Water determined by difference. |
| 1. R. B. Gage (196), analyst. |
| 2. L. H. Bauer (257), analyst. |
| 3. Molecular ratios of no. 2. |
Before the blowpipe the clear crystals assume at once a light-bronze color that darkens on further heating to deep bronze or nearly black, but they do not fuse. In the closed tube they yield water with the change of color. They dissolve at once in warm dilute nitric acid.
Occurrence
Gageite, named after R. B. Gage, of Trenton, N.J., and first described in
a preliminary paper by Phillips (197), was found, associated with zincite,
willemite, calcite, and leucophoenicite, in specimens from the Parker shaft.
The crystals are described as showing faces under the microscope, but none
were measured and no optical data were given.
The best-defined specimens of gageite known to the author are those described at length under pyrochroite (see page 50), which contain distinct crystals with square cross sections but no measurable faces. Their optical characters, determined by Larsen, established their identity with type material studied by him. It has also been determined by optical methods as constituting coatings of silky fibrous appearance and bronze color in cracks in massive ore from the Franklin mines, but sufficient material for a confirmatory analysis has not been found.
In recent years gageite has been found abundantly at Franklin, especially associated with the arsenate chlorophoenicite. It forms pale-pinkish, fibrous aggregates and seems to be a replacement product or a pseudomorph after some unidentified mineral. One specimen, supplied by Captain Rowe, contained sufficient material in a pure state to furnish a gram sample, of which an analysis was made. As Gage's original analysis was made on a very small sample, the confirmation of the composition of the mineral by the new analysis was gratifying.
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Website
© by Herb Yeates 1997-2006.
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This
page created: August 12, 2006 6:18 PM
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