MINERALS INDEX
Friedelite |
| Mn8(OH,Cl)4(SiO3)6.3H2O |
| Hexagonal-rhombohedral-hemimorphic |
Forms
Positive pole: c(0001), q(4045),
and m1(0110).
Negative pole: r1(1011),
s1(15.0.15.2),
and t1(0.15.15.2).
[Combinations on crystals of friedelite]
Crystallography
Friedelite crystals have been described heretofore only from Harstigen, Sweden.
They are rather rough but were measured by Flink and show no trace of hemimorphism.
His value for c = 0.5317, based on measurement of the unit rhombohedron,
is here accepted. All the crystals are implanted by an end, and the free end
was taken as the positive pole.
[Partial angle table of friedelite]
The rhombohedron t1 clearly truncates symmetrically the rhombohedron s1 of the opposite sign and gave better readings than s1, which was assumed to be the form previously determined by Flink, although the readings agree but poorly with it. In no crystal was any measurable face except the base and the rhombohedron q seen on the free end. The base is generally plane, brilliant, and sharply triangular in outline, but the crystals analyzed by Schaller were hexagonal.
Habit
Friedelite is found in markedly hemimorphic crystals, generally as minute
tables but rarely in slender needles. The basal pinacoid is brilliant, but
the other crystal faces are dull and give poor reflections on the goniometer.
Friedelite is also found in fibrous aggregates coating other minerals or forming
stalactites, in lamellar aggregates, and in cryptocrystalline massive form
filling veins.
Composition
Friedelite is a hydrous basic manganese silicate generally containing more
or less chlorine in place of part of the hydroxyl, as shown by some of the
analyses. The computed composition of the chlorine-free mineral and that of
the mineral with a normal amount of chlorine are also given in the table.
The arsenic trioxide found in one analysis may be regarded as derived from
a small amount of included schallerite.
The composition of friedelite and its relation to other members of the group have been treated by Bauer and Berman (260). The following statement is abstracted from their paper.
The formula of friedelite as given by Groth, by Dana, and by Palache (195), is in the orthosilicate form, but Zambonini and later Aminoff considered the mineral as metasilicate, as did Gage, Larsen, and Vassar (233) in comparing the composition of schallerite with that of friedelite. The metasilicate formula appears to give simpler results for the group and is here adopted. The orthosilicate formula of Palache converted into a metasilicate form becomes Mn8(OH,Cl)4(SiO3)6.3H2O.
Friedelite was also identified in extremely small amounts in two small specimens in the Canfield collection. It had the same form as that already describedflattened crystals, with narrow rhombohedral faces and no evidence of hemimorphism, in that respect being like the friedelite found in Europe.
A remarkable specimen of friedelite, now in the Hancock collection at Harvard University, was found in 1909 in the Taylor mine. The specimen contains a triangular cavity, 1-½ by ½ by ½ inch, shown in plate 14, C. The walls consist of a dark-green slickensided chloritic mineral mixed with magnetite, on which is a lining of more definite crystals, set edgewise, of the same chloritic substance. Within the cavity are white tetrahedrons of sphalerite as much as a quarter of an inch on an edge; rhodochrosite in platy rhombohedrons lines one inner surface and massive granular yellow friedelite another; and upon the massive friedelite and last to form in the cavity are implanted crystals of friedelite, which are sharply hemimorphic, the largest being not quite half an inch in diameter, and each is attached to the wall by the rhombohedral end, with a brilliantly lustrous base as the tipper termination. These crystals are the first on which evidence of hemimorphism had been seen (figure 133).
|
|
|
|
On a part of the same specimen, belonging to Mr. Gage, tiny crystals of friedelite were completely embedded in barite, from which they were easily removed uninjured. Though rough and striated they yielded the measurements recorded here. One of them is shown in figure 134. A part of the massive friedelite lining this specimen was analyzed by Gage. (See analysis 5.)
| Figure
134 Stout prismatic crystal of friedelite, showing at the positive pole the forms c(0001) and q(4045), and at the negative pole the forms c1(0001) (as cleavage), and s1(15.0.15.2), and t1(0.15.15.2). Franklin. |
![]() |
Since 1910 numerous specimens of friedelite have been found at Franklin, representing a variety of forms and associations. Fibrous crusts of a dark-red form of the mineral are associated with the fine crystals of tephroite that were found in 1915. (See page 77.) In the Harvard mineral collection there are, besides the specimens already described, one showing films of dark-red friedelite in columnar masses cutting massive garnet with later calcite and willemite, another showing granular yellow friedelite in patches in massive light-green willemite, and another showing a light-yellow crust of crystalline friedelite covering the bases of crystals of green willemite.
Solid veins of compact friedelite as much as 2 inches thick have been found since 1925. In the Stanton collection there were abundant specimens of pale-red friedelite showing thin veins with many cavities, their walls lined with tiny crystals. These specimens came from the 200-foot level south in the footwall pillar 854.
Analysis 4 in the table was made on this material. The crystals are similar to those of figure 134 but lack the positive rhombohedron q. Calcite and barite are the only associated minerals in these veins.
In another group of specimens veins of compact brown friedelite have open spaces whose walls are covered with light-yellow crystalline crusts. Although not measurable, the slender needles are clearly hemimorphic and are well represented by figure 135, except that they appear more slender. With them are the hematite crystals described on page 42.
| Figure
135 Slender hemimorphic crystal of friedelite showing the form c(0001) at the positive pole; the forms c1(0001), as cleavage, and s1(15.0.15.2) at the negative pole; and m1(0110). |
![]() |
At Sterling Hill friedelite has also been found forming veins and stringers and mixed with calcite, cutting the massive ore. It is of lively pink color and is mostly compact but with scattered drusy cavities. A specimen from the 1,300-foot level, stope 720, with a specific gravity of 3.014, was analyzed by Mr. Bauer. Although it differs somewhat in composition from the other analyzed material in its high magnesia and alumina, it is undoubtedly to be regarded as a low chlorine friedelite.
|
|
||
|
Website
© by Herb Yeates 1997-2006.
|
||
|
This
page created: August 12, 2006 6:17 PM
|
||