FRANKLIN AND STERLING HILL NEW JERSEY: THE WORLD'S MOST MAGNIFICENT MINERAL DEPOSITS
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SULFATES BORATES TUNGSTATES AND MOLYBDATES ARSENATRES ARSENIDES PHOSPHATES AND VANADATES UNNAMED MINERALS


Sulfides

ACANTHITE

ARSENOPYRITE

BORNITE

CARROLLITE

CHALCOCITE

CHALCOPYRITE

COVELLITE

DIGENITE

DJURLEITE

GALENA

GERSDORFFITE

GREENOCKITE

HAWLEYITE

MARCASITE

MOLYBDENITE-2H

PYRITE

PYRRHOTITE

SPHALERITE

STIBNITE

WURTZITE


Arsenides and antimonides

BREITHAUPTITE

CUPROSTIBITE

DOMEYKITE

LOELLINGITE

NICKELINE

PARARAMMELSBERGITE

RAMMELSBERGITE

REALGAR

SAFFLORITE

SKUTTERUDITE


Sulfosalts

BAUMHAUERITE

BERTHIERITE

SELIGMANNITE

TENNANTITE

TETRAHEDRITE

ZINKENITE

(Cu,Fe)12As4S13                                                    Cubic

 
 
 
  Figure 21-38. Crystal drawing of tennantite from Sterling Hill. Drawing is from Palache (1935) who provided crystallographic data.  
   

Tennantite was first found at Sterling Hill by Lawson Bauer and confirmed by Palache (1928a, 1935). Reflected-light studies indicate it is commonly present as an accessory mineral in the late sulfide veins at Franklin and Sterling Hill.

Description

Sterling Hill tennantite has been observed megascopically only on the material described by Palache (1928a). Here it occurs as 2-3 mm, equant crystals with {111}, {110} and {211} as the dominant forms, as illustrated by Palache (Figure 21-38).

This tennantite is deep red, appearing black upon casual observation, and has a metallic luster and no cleavage. It could be confused with some single-crystal hematite.

Composition

Tennantite is a copper iron arsenic sulfide mineral. Preliminary analysis of the original material yielded a composition of (Cu9.99Zn1.24Fe0.77) (As3.69Sb0.31)S13. Analysis of a specimen with loellingite, from a separate assemblage described below, yielded Cu 43.05, Zn 5.65, Fe 3.1, As 19.1, Sb 1.25, S 28.0, total = 100.15 wt. % (E. A. J. Burke, pers. comm.). This yields, on the basis of 12 (Cu,Fe,Zn), the composition (Cu9.92Zn1.27Fe0.81)(As3.73Sb0.15)S12.78, very close to the composition of the original material and demonstrating that both specimens have Zn > Fe.

Occurrence and paragenesis

The original find of tennantite was on the 900 level at Sterling Hill. Here it occurs in a vein, and coats an assemblage of actinolite, feldspar, titanite, and epidote, and is in turn coated with stilbite crystals.

Tennantite also was found intimately associated with bornite and loellingite on the 1300 level and with bornite, chalcopyrite, galena, and sphalerite on the 800 level. It was seen, but not studied, in a number of the sulfide veins, always sparse and associated with bornite and sphalerite.

Jenkins and Misiur (1994) reported it from below the 700 level, with an Sb:As ratio of 15:85, associated with chalcopyrite, galena, and other minerals.

 

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Copyright © 1995 by Pete J. Dunn
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CHAPTER 21. SULFIDES, ARSENIDES, ANTIMONIDES, AND SULFOSALTS