FRANKLIN AND STERLING HILL NEW JERSEY: THE WORLD'S MOST MAGNIFICENT MINERAL DEPOSITS
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ARSENIC

COPPER

GOLD

GRAPHITE

LEAD

SILVER

SULFUR

ARSENIC

As
Hexagonal

 
 
 
  Figure 20-1. Crystal drawing of arsenic from Sterling Hill. Drawing is from Palache (1941b) who provided crystallographic data.  
   

Arsenic was first reported from Sterling Hill by Palache (1941b) and has not been reported from Franklin. The known arsenic specimens consist of rare 0.5 to 5 mm crystals and blebs of dark gray, massive material up to 2 cm.

Palache measured and illustrated a flattened rhombohedral crystal and indentified the forms present (Figure 20-1). Arsenic is easily oxidized, and the known specimens have a black crust which is a mixture of arsenic and arsenolite, as identified employing XRD techniques. It is not known, however, if the arsenolite formed naturally before chemical dissolution of the host calcite in a laboratory process or formed contemporaneously with calcite-dissolution, or subsequently. Arsenolite, therefore, is not listed as a species from these deposits. Studied Sterling Hill arsenic is Sb-free and twinned on a microscopic scale.

Arsenic was found on the 900 level at Sterling Hill, where it occurs in a calcite matrix, associated with realgar, arsenopyrite, graphite, pyrite, zinkenite, and other minerals. A similar assemblage was found subsequently on the 1100 level, as mentioned under realgar, but arsenic has not as yet been indentified from this material.

 

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CHAPTER 20. ELEMENTS